The Microwave Plasma Enhanced Engineering Essay

When diamond is mentioned, people will automatically believe about the cost that valued by the society. Why diamond, a type of gemstones, will be so much more than others? Diamond is non merely a shinny rock. It has a batch of great and alone belongingss such as highest hardness and thermic conduction of any bulk stuff. These belongingss determine the major industrial application of diamond in cutting and polishing tools. Besides, the optical feature is something that must be discuss in diamond. With highly stiff lattice, the optical features become important. However, diamond still can pollute by few types of drosss, such as B and N, which consequences in some colour for diamond. In this paper, a reappraisal of diamond will be presented.

How diamond is made

Naturally, diamonds are formed at high force per unit area and high temperature conditions bing at deepnesss of 140-190 kilometer in the Earth mantle. They are bought near to Earth surface through volcanic eruptions by a magma, which cools into pyrogenic stone known as kimberlites and lamproites. Figure 1shows a stage diagram of C. From Figure 1, diamond is stable at high force per unit areas and temperatures. Graphite, nevertheless, is the stable signifier of C under ordinary temperature and force per unit area conditions. One method of synthesising diamond is to subject graphite to conditions of about 55,000 ambiances and temperatures of about 2000 & A ; deg ; -C. However, even though C is non at the minimal energy province, it does non spontaneously convert from diamond to graphite. Since we know that diamonds are form at high force per unit area and high temperature. Research originally synthesis diamonds under same conditions, high force per unit area high temperature ( HPHT ) .

Figure 1 Phase diagram for C. At sufficiently high temperatures and force per unit areas diamond is the stable. At lower temperatures and force per unit areas, black lead is the stable signifier. Under ordinary conditions for temperature and force per unit area, near 1 standard pressures and room temperature, diamond may be considered a metastable signifier of C. ( Reinhard )

The everyday belongingss of diamond such as hardness and high thermic conduction make it an of import new stuff in a broad scope of applications. However, the high cost of stuff production has limited the commercial used of diamond thin movies to a few applications. Today the engineering is able create artefactual diamond by chemical vapour deposition ( CVD ) . CVD is a method of bring forthing man-made diamond by making the fortunes necessary for C atoms in a gas to settle on a substrate in crystalline signifier. It is common to happen grammatical crystals with about equal development of ( 111 ) and ( 100 ) faces ( Figure 2 ) . ( DeVries ) Diamond grows by CVD frequently involves feeding changing sums of gases into a chamber, stimulating them and supplying conditions for diamond growing on the substrate. The gases include a C beginning and typically include H every bit good. However the sums used depends on the type of diamond being grown. In CVD of diamond, the factors driving cost include low reagent use, low deposition rates, high-energy ingestion, big thermic direction tonss at the substrate, and capital equipment costs. For successful consequence, diamond deposition depends on different chemical and conveyance procedures happening in the gas stage and on the surface. ( See Figure 4 for the ascertained forms of as-grown natural diamonds, high temperature high force per unit area ( HPHT ) grown synthetics and chemical vapor deposition ( CVD ) grown diamonds, including the measure patterns on the different faces )

Figure 2 Diamond crystals from CVD deposition. The largest dimension is about 20 jlm. ( DeVries )

All diamond CVD processes under a extremely energetic activation phase in the gas stage. It lead to two intents which are to disassociate the hydrocarbon precursor molecule into fragments that react more readily at the deposition surface and to disassociate molecular H to make a superequilibrium concentration of gas-phase H atoms. ( See Figure 3 for different technique of C dissolved in H vs. temperature ) Hot-filament reactors, microwave plasma reactors, DC arcjet reactors, and burning are most commonly energy used as diamond CVD reactors. These reactors have a few common characteristics and that ‘s why they are able to bring forth high quality diamond movies. They all have a big sum of energy, in the signifier of electrical or chemical free energy, is input to accomplish dissociation of molecular H and the hydrocarbon feedstock. Reasonably low force per unit areas are used to forestall three-body recombination of H to organize molecular H. High gas-phase temperature is produced in the activation zone, and inactive or active chilling is employed to keep a substrate temperature in the vicinity. However, they are different from the conveyance processes. Hot-filament and microwave plasma are dominated by diffusion which mean there is no thermic, speed, or concentration boundary bed. Linear gradients in temperature, speed, or species concentration between the excitement part ( hot fibril or plasma ball ) and the deposition surface in both reactors are frequently found. However, the disadvantage is growing rate is slow. DC arcjet CVD and burning is characterized by high speeds ; thin boundary beds in temperature, speed, and concentration are formed near the growing surface. In the followers, the item of each technique will be introduced.

Figure 3 Differential solubility of C in H for different CVD diamond methods.

Figure 4 Idealized morphologies of natural, HPHT-grown and CVD-grown diamonds. For the { 111 } and { 100 } faces characteristic orientations o f growing stairss are besides indicated. ( Nazare and Neves )

High force per unit area and high temperature ( HPHT )

Artificial Diamond is original made by high force per unit area and high temperature ( HPHT ) It is still widely used because of it ‘s comparatively low cost. It is typically processed under a force per unit area of 5GPa at 1500 & A ; deg ; C. There are two common systems ; Belt system and Bars system. In belt system, a immense hydraulic imperativeness with anvils and a ring molded construction are used. The upper and lower anvils supply the force per unit area burden to a cylindrical inner cell and a belt of pre-stressed steel sets confines the internal. Anvils serve as electrodes and supply electrical current to the compressed cell. A fluctuation of the belt imperativeness uses hydraulic force per unit area to restrict the internal force per unit area. Figure 5 is a conventional illustration of a belt system where diamond seeds are placed at the underside of the imperativeness. While the internal portion of imperativeness is heated, the liquefied metal dissolves the high pureness C beginning. The liquefied metal so transports to the diamond seeds and precipitates. Colorless diamond can be synthesized if the N is removed by blending little sum of Ti with the metal. ( International Diamond Lab )

Figure 5 aˆ?This is a conventional illustration of a Belt type HPHT imperativeness. ( International Diamond Lab )

BARS system is developed at the Russian Academy of Sciences in Novosibirsk. It is really similar to the belt type system. It is made up by eight outer anvils with a spherical outer form to which force per unit area is applied and six inner anvils to multiply the force per unit area to the sample. BARS system is the most compact, efficient, and economical of all the diamond-producing imperativenesss. ( International Diamond Lab )

Hot-filament CVD

Hot-filament CVD is besides called thermally activated CVD. It is one of the earliest developed attacks to low force per unit area synthesis of diamond. A furnace lining metal, normally tungsten, is used as a fibril, is heated to high temperature around 2300 & A ; deg ; C. The temperature can be reach by opposition warming and the high temperature aid to trip the hydrocarbon-hydrogen gas mixture. The fibril is located a few millimetres above the substrate besides provides warming for the substrate. The hydrocarbon-hydrogen gas mixture is allowed to flux across the hot fibril, where it is activated. Hot-filament CVD reactors are cheap and easy to build. The filament temperature, the place of the substrate with regard to the fibril, and the gas flow kineticss play of import factors in the procedure. However, there are several disadvantages of this technique such as taint of the diamond movie by the fibril, eroding and sagging of the fibril, and a comparatively slow growing rate. It is besides necessary to provide changeless power throughout a deposition utilizing a proper power accountant but the uniformity of the substrate temperature is hard to keep when utilizing multiple fibrils. ( Reinhard )

Figure 6 Conventional diagram of the hot fibril CVD procedure demoing the basic elements.

Microwave plasma-enhanced CVD ( MPECVD )

Microwave plasma enhanced CVD is widely used for diamond deposition. A magnetron is normally used to bring forth micro-cook energy at 2.45 GHz and a wave-guide assembly is used to match the energy to a resonating pit. MPECVD is an electrodless procedure, which is an advantage over other techniques, and there is no taint from the electrode stuff. The microwave plasma excitement of H generates superequilibrium concentrations of atomic H. The hits of negatrons with gas atoms and molecules generate high ionisation fractions. ( Reinhard )

Figure 7 Conventional apparatus of the CVD synthesis of diamond. ( Markus )

Direct current ( DC ) arcjet discharge technique

DC arcjet discharge is a really high growing rate procedure. Normally, this technique will be usage to synthesis midst and freestanding diamond substrates. A DC arcjet discharge reactor for diamond deposition consists of a gas injection nose, composed of a rod cathode, which is normally made of wolframs, concentric with a tubing anode. Gass are allowed to flux between the cathode and anode. Gass will be spray out from an opening in the anode so a high temperature discharge jet is created and sustained by a DC electromotive force across the electrode. The substrate is located downstream from the jet watercourse on a water-cooled substrate phase. Carbon precursor and graphite etchant gases would be introduced at different locations depending on the coveted activation temperature. Although this technique is frequently used because of the high growing rate, there is several disadvantages of it such as the movie can undergo from high compressive emphasiss, microvoids, and high surface raggedness. ( Reinhard )


Combustion is good cognize for its scalable nature, minimum public-service corporation demands, and significantly cut down capital costs relative to plasma assisted procedures. The most of import parametric quantity in burning synthesis is the oxygen-to-acetylene ratio, defined as

R = O2: C2H.

At values of R near 1.0, a impersonal fire is achieved, which is defined as the status where the feather part merely disappears because all the ethyne is consumed in the primary fire. The diamond growing regimes as a map of composing are showed in Figure 9. The highest quality diamond is obtained in somewhat rich fires, when oxygen-to-acetylene ratio is about 0.85-1.0. The value of R at which a impersonal fire occurs is dependent on both burner design and entire flow rate. Substrate temperature is control in a scope from 950-1650K during burning CVD. With high temperatures, substrates has been limited to stuffs such as Si, aluminum oxide, and diamond. However, it is non easy to mensurate the substrate temperature in burning CVD due to the utmost heat fluxes present. Substrate temperature controls growing rate and morphology. As the substrate temperature additions, the growing rate is relative. ( See Figure 9 ) However, after the growing rate reaches its upper limit, an look of a rapid diminution in both the quality and the growing rate is observed. ( Reinhard )

Figure 8 Two designs of atmospheric level fire burners: ( a ) a coflow design and ( B ) a cornet bell design ( Reinhard )

Figure 9 The consequence of substrate temperature on growing rate observed in burning CVD of diamond. In atmospheric torches the maximal growing rate occurs at substrate temperatures between 1450 and 1650 K ( Reinhard )


Diamond is uncommon because of two grounds. First, the dynamicss of graphite formation are much faster than the dynamicss of diamond formation in normal status. Second, a big activation energy barrier between black lead and diamond prevents thermic activation of diamond into black lead. ( See Figure 10 ) When diamond is synthesized under conditions where black lead is the stable stage of C, the consequence of synthesising diamond is normally failed. It is because the denseness of diamond is greater than the denseness of black lead. ( Anthony )

At ordinary temperatures and force per unit areas, although diamond is non the minimal energy province of C, it is besides non an unstable phase of C. ( see Figure 1 ) Therefore, if C atoms are in the diamond lattice spacial agreement, the solid does non spontaneously change over to graphite under low temperature, low force per unit area conditions. Formation of diamond from nascent C incorporating species under metastable conditions is both thermodynamically allowed and readily achieved under proper deposition conditions. It is the lower temperatures and force per unit areas associated with this method of diamond synthesis that have offered the capableness of direct deposition of diamond on a assortment of substrates and have opened the possibility of new applications of diamond. For many such applications, the diamond thickness demand be merely on the order of microns ; hence the constructions are referred to as diamond movies. ( Reinhard )

Figure 10 Energy diagram of C ( Anthony )


Pure diamond is composed merely by C and arranged in the diamond lattice. ( See Figure 11 In theory, pure diamonds are crystalline and colorless. ) In diamond lattice, each C atom has four nearest neighbours in the tetrahedral agreement associated with sp3 chemical bonds. The nearest neighbour distance is 1.54 & A ; Aring ; and the unit cell dimension is 3.567 & A ; Aring ; . The denseness of diamond is 3.515g/cm3. The measure of diamond is normally referred to carats, where one carat is equal to 200mg. ( Reinhard ) However, quality of diamond is considerable because both natural and man-made diamond may incorporate drosss and defects. Diamonds occur in assorted colour and these are caused by defects, including replaced drosss and structural defect. These defects will impact the light soaking up. Therefore, diamonds are characterized into type I, type II and some subtypes, with the former containing N as an dross and the latter being basically nitrogen free. ( John, Polwart and Troupe )

( a ) ( B )

Figure 11 a ) Conventional diagram of carbon-carbon bonding in diamond and black lead ( Anthony ) B ) 3D diamond lattice

Type I

Type I diamonds in which impurity-related optical and paramagnetic soaking up are dominated by N defects. Normally, type I diamonds are crystalline to 300 nanometers. ( Robertson R. ) In general, the dross content of natural type I diamonds is more varied compared to that of type II diamonds. The most apparent difference between type I and II diamonds comes from IR soaking up spectra, which are considered to be the chief standard for this distinction. ( See Figure 12 for Refraction index of type I and type II ) About 98 % of natural diamonds contain nitrogen with concentrations noticeable in optical soaking up. 74 % of them have a N content high plenty to be decidedly classified as type I. Nitrogen is regularly nowadays in natural diamonds at degrees every bit high as 200 to 4000 ppm. ( Zaitsev ) In type I, there are three subtypes, type Ia, type Ib, and type Ic. Type Ia contains N in farily significant sums of the order of o.1 % which most natural diamonds belong to this type. Type Ib besides contains N but in spread substitutional signifier which most of man-made diamonds are this type. ( Markus ) Type Ic include diamonds that contain high concentration of disruptions. Even type Ic does n’t truly related to contaimination of N but the feature of type Ic is categorized in type I. Type Ic has the absoption continuum at wavelength below 900nm and a extremum at 560nm. ( Zaitsev )

Figure 12 Refraction index of type IIa and type I natural diamonds in the UV spectral part ( Zaitsev )

Type II

Type II includes diamonds demoing no optical and paramagnetic soaking up due to nitrogen-related defects. The measure of N found in type II is really small. ( Below 1017cm-3 ) Type II diamonds are exhibited optical transparence up to 230 nanometers ( Robertson R. ) . However, it is rare to happen natural diamonds without nitrogen-related defects in soaking up. Merely 1 to 2 % of type II diamonds are found in nature. ( Zaitsev ) There are two subtypes are in type II, type IIa and type IIb. Type IIa is non effectual by N and this type of diamonds has enhanced optical and thermic belongingss. However, they are rare to happen in natural. Type IIb is a really pure type which has semiconducting belongingss and this type of diamond is normally find in bluish and highly rare in nature. ( Markus )

Influence of defects and dross

Nitrogen does non strongly act upon the refractile index of diamond in the seeable spectral part. Therefore the refractile index for types I and II natural diamonds may non differ by more than 1 % . ( Robertson R. )

Since there is no definite inclination for discriminatory double refraction of diamonds of any type, it indicated that nitrogen dross does non straight act upon the double refraction of diamond. However there is a tendency such that natural diamonds of mean size, with an enhanced double refraction, are ultraviolet conveying. Diamonds with a low double refraction are normally ultraviolet-opaque and N is the caused for this consequence. Diamond with low N, type II, have a really distorted stressed crystal lattice. ( Zaitsev )

The double refraction of diamond is caused by fictile distortion, elastic distortion near inclusion, growing striations, growing sector boundaries, disruptions, grain boundaries, and diamond-substrate boundaries. The phenomena occur in both types of diamonds. The highest double refraction is found in fragments of natural diamonds where dodecahedral diamonds shows the least double refraction. Defects arises from sheets of stacking mistakes are expected to ensuing the double refraction contrast weaker than from partial disruptions. However, partial disruptions or stacking fault sheets will be seen merely the background double refraction is really low. ( Zaitsev )


Diamonds have some great belongingss that other stuff still can non be compared and that is the ground why people would wish to understand how diamond is formed and synthesis diamond to cut down the cost of the stuff. Diamond is good known for high thermic conduction, high electrical electric resistance, low coefficient of clash, high grade of chemical inertness, high optical scattering, big energy spread, low infrared soaking up, and high dislocation electromotive force. See Table 1 for outstanding belongingss of diamond.

Table 1 Some belongingss of diamond ( Markus )

Thermal Properties

As mentioned, diamond has high thermic conduction. For high quality individual crystals, normally type IIa, the thermic conduction, ? , is about 22W/cm & A ; deg ; C at room temperature. This belongings is due to the stiffness of diamond bond and the diamond construction, which rise to a high acoustic speed and a really high characteristic temperature. Recently, research worker has reported the best thermic conduction of the movie is about 11W/cm & A ; deg ; C. For midst movie, the conduction is about17W/cm & A ; deg ; C at room temperature. ( J.E. Graebner ) Figure 13 indicates the relation between thermic conduction and movie thickness, where thermic conduction additions with movie thickness. Thermal conducitivy besides depends on grain boundary. Diamond ‘s thermic conduction additions with decreasing temperature, making a upper limit of 42 W/cm-K near 80 K, after making the upper limit the thermic conduction lessenings. Impurities, such as N, cut down the thermic conduction. Type I diamonds with 0.1 % N merely have 50 % thermic conduction values of type II diamonds in room temperature. Isotropic pureness increases the thermic conduction. Man-made diamond crystals grows with pure carbon-12 have thermic conductions 50 % higher than those of natural diamond for which the atomic weight is 12.01 because the stuff contains 1.1 % carbon-13. ( Zaitsev )

Figure 13Measured thermic conduction at 25 & A ; deg ; C for five samples ( squares ) . Solid circles show the derived conduction. The horizontal dotted line indicates the typical conduction reported for individual crystal high quality ( Type IIa ) diamond. ( J.E. Graebner )

Optical Properties

Diamond movies are normally crystalline in the infrared, with the exclusion of the carbon-hydrogen absorbing sets centered at about 2900cm-1, weak absorbing in the seeable spectrum, and increasing absorbing with diminishing wavelength in the UV visible radiation. The optical spread value is range from 0.38 to 2.72 for diamond movies. ( A. )

The index of refraction, both the existent portion N and fanciful portion K, and its spectroscopic fluctuation has been found to be dependent on the readying conditions and H content of the movies. Its value at 632.8 nanometers can be adjusted from 1.7 to 2.4 by seting the deposition conditions. ( A. ) This refractile index is big comparison to other crystalline stuff. With big refractile index, it is besides found big contemplation coefficient and a little angle for entire internal contemplation. ( Zaitsev ) The index of refraction is besides affected by the H content in the diamond movies and by and large additions with diminishing concentration of edge H. It is, nevertheless, dependant on the concentration of edge H and non entire H content in the movie. A higher index of refraction normally indicates diamond with stronger crosslinking, higher hardness, and better wear opposition. ( A. )

Diamond is besides photoconductive. There is a strong photoconductive extremum at 225 nanometers due to excitement of negatrons across the set spread in pure diamond, and in B doped diamond there are besides peaks from 1.4 to 3.5 ?m due to excitement of the deep-lying acceptor degrees. ( Reinhard )

Electrical belongingss

The electrical belongings of diamond movie is good known for big set spread. Diamond have a modest bandgap. The energy set construction of diamond exhibits an indirect energy spread with a value of 5.47 electron volt at 300 K. This is sufficiently big that at near room temperature the intrinsic bearer concentration is negligible and the stuff is an dielectric with a dielectric invariable of about 5.7. ( Zaitsev ) ( See Figure 14 for set construction ) In an dielectric the valency negatrons form strong bonds between neighbouring atoms and accordingly these bonds are hard to interrupt. Thus, the bandgap is big and there are no free negatrons to take part in current conductivity at or near room temperature. ( Markus )

Figure 14 Activation energies for some drosss in diamond. B is boron for P type, P is phosphorus for n-type, and N is nitrogen. ( Markus )

The set construction of diamond movie is assumed to dwell merely a mobility spread, where bearers shacking in spread provinces are localized. The mobility spread produces semiconducting material behaviour, nevertheless, the high denseness of localised spread provinces leads to low apparent bearer mobilities and significantly degrades the semiconducting belongingss of stuff. Diamond movies normally have high electrical electric resistances from 102-1016? , depending on the deposition status ( A. ) The electrical conduction of diamond is more sensitive to drosss than the thermic conduction. The electrical electric resistance can be reduced by several orders of magnitude through incorporation of metals or N in the movies. The lessening of electric resistance by incorporation of dopants possibly related to a dopant induced graphitization. However, more groundss are needed to turn out.

Boron doped p-type diamond exists in nature. The growing of B doped diamond movies by CVD techniques has been achieved by adding B incorporating molecules to the gas mixture in either a microwave or in a hot fibril reactor ensuing in the growing of B incorporating p-type diamond movies. ( A. ) ( R. )

N-type doping is much more complicated. It is still questionable about the possible giver atom that will give a shallow plenty energy degree in the spread to be sufficiently ionized at room temperature. Most late clear giver activity is phosphorus doped for n-type diamond. In Figure 15, the dependance of the electric resistance on measurement temperature. Similar inclines are obtained for all samples proves that in this temperature run the conductivity mechanism is thermally activated, with an activation energy of 0.46 electron volt, instead independent of growing conditions. ( R. )

Figure 15 Temperature dependance of the electric resistance of n-type diamond, doped with different sums ( ppm ) of P ( 300,800 K ) . ( R. )

B. Mechanical Properties

Diamond is the hardest known substance. Diamond besides has the lowest squeezability, the highest elastic modulus, and the highest isotropous velocity of sound ( 18,000 m/sec ) of any known materia ( Nazare and Neves ) . The grade of hardness is quantified in footings of both opposition to indenture and scratch ( or abrasion ) opposition.

In footings of squeezability, the ratio of tensile emphasis to linear strain, or Young ‘s modulus, is 1050 GPa, a value about five times higher than that of steel. However under different methods of proving, the Young ‘s modulus is different and C11, C12, C44. Table 2 provides the Young ‘s moduli of diamond with different trial methods. Because of its brickle nature, diamond is non peculiarly strong. ( Markus )

Table 2 Elastic moduli of diamond ( GPa ) ( Nazare and Neves )









X raies








The mechanical strength of diamond is influenced by a figure of important factors, including the applied emphasis system, the ambient temperature and the grade of both internal ( drosss ) and external ( surface coating ) flawlessness. Fracture occurs when a certain degree of emphasis is applied and the manner of failure will be that which requires the smallest emphasis. Materials, where the bonding is preponderantly covalent or where there is a significant grade of covalent bonding, have a big built-in lattice opposition to dislocation gesture and failure occurs at low emphasiss, below the theoretical break emphasis. Diamond, as with any other crystalline stuff, can neglect by either brickle break, cleavage, or in a ductile manner, flow by a shear procedure. Although thermic belongingss and electrical conduction are both extremely affected by N, there is no clear grounds found that mechanical belongingss are clear related to N. ( Nazare and Neves )

Highly inert chemically

Diamond is extremely inert chemically, except for two state of affairss. It is susceptible to oxidising agents at high temperatures. For illustration, if diamond is heated in the presence of O, oxidization Begins at around 900 K. Besides, diamond is capable to chemical onslaught by certain metals at high temperatures. These include carbide formers such as wolframs, Ta, Ti, and Zr every bit good as dissolvers for C such as Fe, Co, manganese, nickel, Cr, and Pt. ( Zaitsev )


Diamond is a really utile stuff because of the outstanding belongingss including high thermic conduction, high electrical electric resistance, low coefficient of clash, high grade of chemical inertness, high optical scattering, big energy spread, low infrared soaking up, and high dislocation electromotive force. With these belongingss, diamond is used for diverse application besides jewellery. They are normally used in mechanical application, optical applications, thermic applications, and sensor applications. Diamond can be used for scratchy and wear opposition coating for cutting tools, lenses, Windowss for power optical masers, diffractive optical elements, heat sinks for power transistors, semiconducting material optical maser arrays, solar blind photodetector, and radiation hard and chemically inert sensors.

Table 3 Future application countries for diamond electronics. ( Markus )

Film editing Tools

Single crystal diamond is used for coating of modulated or layered composing of two or more passage metal compounds. It is common to utilize diamond coating for certain types of crunching wheels or cutting of extremely scratchy metals and metals. There are two ways to use diamond on to the film editing tools. First, turning comparatively thick beds of CVD diamond from which separate freestanding pieces are obtained. These pieces are so brazed onto a cutting tool. Second, straight deposited diamond onto the film editing tools. ( Markus ) Often, high-quality diamonds are selected for usage in dressing tools for non-ferrous metals, aluminium, brass bronze, ceramics, black lead, and glass fiber-reinforced construction. ( Markus ) ( Hammond and Evans ) Single-point diamond is mounted in a metal matrix. They are normally used to dress and leave or reconstruct the needed geometric form to certain scratchy wheels. Two typically signifiers of such film editing tools are single-point and multi-point. Today, individual or multi-point cutters include milling, turning, drilling, cutting-off and slitting. ( Hammond and Evans )

Demonstrated surfacing diamond onto hardmetals

Hardmetals are the most valuable and of import substrates for coated tools, due to their intrinsic belongingss and their broad scope of mechanical belongingss. They consist of WC and Co with add-ons of TiC, ( Ta5Nb ) C, and VC, which chiefly change their hardness and wear opposition. The sum of Co binder is mostly responsible for ductileness or crispness. Hardmetals have been used as wear parts and film editing tools for decennaries, with and without surfacing applications.

Normally, successful diamond coatings on WC-Co substrates have no or a really low sum of three-dimensional carbides ( TiC ) and besides a comparatively low Co content. Both Co and TiC add-ons increase the thermic enlargement coefficient of the hardmetal and cut down the adhesion of the diamond coating. A high Co vapour force per unit area and its high mobility on the substrate surface influence diamond deposition. In the gas stage environing the substrate surface, Co catalyses the formation of nondiamond C stages, which can be deposited at the interface prior to the diamond formation. How and why the Co drops reach the diamond coating surface is non yet to the full understood. Surface forces might play an of import function ( See Figure 16 ) .

Figure 16 Co as portion of the hardmetal binder stage and its influences on the diamond deposition

Electrochemical Applications

Electrochemical behaviour of boron-doped CVD diamond is one of the most promising applications of conductive diamond. Boron doped diamond fits the demand for an electrode operates inertly and without impairment in rough chemical environments. Compare to platinum electrodes, diamond electrodes provide a much wider potency scope over which no important H2O decomposition occurs. ( Reinhard ) Diamond electrodes are suited substrates for reactions crossing a broad possible scope in aqueous solutions. They besides have the advantage of chemical stableness, even in extremely aggressive environments. In Figure 17 the I-V curves obtained with a B doped CVD diamond electrodes in assorted ( KI, KBr, and HCl ) solutions are shown. The behaviour of the doped diamond electrode is much superior to that of the commonly used baronial metal electrodes. Diamond bears as a stuff for the fiction of cold cathode or other negatron breathing devices requires the diamond to be electrically conductive, with no demand for an accurately known doping degree. ( R. )

Figure 17 Current V. Potential of a extremely B doped CVD diamond electrode in ( a ) 1 M KI ; ( B ) 1 M KBr and ( degree Celsius ) 1 M HCl. Scan rate 150 mV/s.

The alone negatron emanation belongingss of diamond are the most promising applications of semiconducting diamond. Although, no clear apprehension of the natural philosophies that determined the negatron emanation from diamond emerges. There are still many applications such as field emanation from diamond surfaces utilizing diamond to conductive.

Thermal Management

The high thermic conduction of diamond, combined in some instances with its chemical inertness and high electrical electric resistance, makes it of involvement for a assortment of thermic direction applications. Laser diamond heat sinks and other thermic direction substrates formed from CVD polycrystalline diamond are illustrations of available merchandises. Because diamond combines exceptionally high thermic conduction with exceptionally low electrical conduction, it is of considerable involvement in electrical packaging applications. It provides efficient waies for heat flow without compromising the electrical isolation of single constituents. ( Reinhard )

Transmission Applications

Diamond provides a window with high transmission for assorted parts of the electromagnetic spectrum. It is an ideal radiation window stuff in peculiar for applications affecting high power degrees and mechanical, thermic or chemical burden. Due to its big bandgap ( 5.5 electron volt ) and the deficiency of infrared active cardinal vibrational manners, diamond is optically crystalline over a big wavelength scope. Even at elevated temperatures, diamond remains crystalline, since the big bandgap does non let the formation of free bearers. In the x-ray part of the spectrum, diamond is of involvement for x-ray lithography masks. The low atomic figure of diamond consequences in low x-ray soaking up. Another illustration is in high-octane gyrotrons such as are used in merger research. This application requires the transmittal of really big powers ( megawatts ) at microwave frequences ( 170 GHz ) every bit good as the ability to disperse heat quickly. The ability to convey high powers in the optical part of the spectrum is of involvement to laser interior decorators because the design of high-power optical masers is power limited by harm bounds to laser optics instead than restrictions of the optical maser medium or pumping mechanisms. The abrasion opposition and chemical inertness make diamond of involvement as an optical coating stuff every bit good. ( Reinhard )

Diamond is known for its broadband optical transparence covering the UV, seeable, close and far IR. In this scope the optical transmittal exhibits merely minor intrinsic soaking up sets originating from two- phonon ( 1332-2664 cm-1 ) and three-phonon ( 2665-3994 cm-1 ) passages. The maximal soaking up coefficient sums to 14 cm-1 at 2158 cm-1. This holds true for optical class CVD-diamond as shown in Figure 18. The soaking up around 10 ^m is of peculiar involvement for CO2-laser constituents and because many IR detectors operate within the 8-12 ?m atmospheric window. ( Nazare and Neves )

Figure 18Transmission spectrum of a high-quality CVD-diamond window ( thickness: 150 ?m ) ( Nazare and Neves )

CVD-diamond is besides used as vacuity Windowss for high-power microwave ( Gyrotron ) tubing. These Gyrotron tubings are used for the negatron cyclotron warming of merger plasmas. Power degrees transcending 1 MW at frequences of around 100 GHz have been demonstrated. Until late the end product window of these devices has been the most critical constituent restricting the maximal end product power or the pulse continuance. In this context CVD-diamond window with H2O edgecooling is found to be really promising. The highly high power degree requires really low insulator losingss. CVD-diamond exhibits loss tangent values every bit low as 10-5 ( at 140 GHz ) . Below 350-400 & A ; deg ; C there is practically no temperature dependance. In the 10- 145 GHz range the loss tangent decreases with frequence as 1/f [ 27 ] or as 1/f05. ( Nazare and Neves )

X-ray lithography masks

The declaration bound of optical lithography is defined by diffraction and sprinkling as the characteristic size approaches the exposing wavelength. X ray lithography, which uses significantly shorter radiation ( 0.8-1.5 nm versus 300-400 nanometer ) , offers a proficient way to accomplishing the higher declaration. However, several factors have delayed the execution of X-ray lithography on the production line for IC fiction.

The major non-technical factor is related to the immense constitutional optical technological substructure which has continued to do important betterments by utilizing measure and repetition exposure tools, integrating multilevel resist, using contrast foils, utilizing shorter wavelength radiation, planing higher numerical aperture optics, which has efficaciously delayed the execution of X-ray lithography. The proficient barriers to X-ray lithography execution include the absence of a dependable, high volume, low defect denseness X-ray mask engineering, a high velocity X-ray resist, a high velocity, low cost exposure/alignment tool.

The best mask stuff has low atomic figure since the X-ray transparence improves with diminishing atomic figure. TABLE 1 reveals the failing of polymers as membrane stuff campaigners. They are non merely hygroscopic but are automatically soft and hence easy distorted. The metals Ti and Be are reasonably stiff ; nevertheless, their opacity is troublesome, but non pathological, since alliance Windowss can be etched in the membrane after overcoating with polyimide to back up the alliance form. Beryllium would be first-class were it crystalline, dismissing its toxicity. Si and its nitride and oxide are good from an X-ray and optical transparence point of view but lack the mechanical stiffness of the furnace linings like SiC, BN and diamond. Si has the important advantage of a big installed engineering base and capital equipment handiness. As can be seen, diamond has the highest stiffness factor S of any stuff. There are other factors to see in choosing a stuff such as: scale-up of fiction procedure, X-ray-induced debasement, surface smoothness, two-dimensionality, secondary negatron emanation induced by the X raies, adhesion of metallization. Diamond ‘s low mass soaking up coefficient and low denseness make it compatible with a assortment of X-ray beginnings. ( Nazare and Neves )

Table 4 Comparison of stuffs based on X-ray transparence Texas, optical transparence to, and mechanical stiffness S. ( Nazare and Neves )


Texas ( ?m )


S = Et0Z ( I-V ) ( GPa



& A ; gt ; 5




& A ; gt ; 5




































Detectors and Detectors

Diamond-based devices are besides of involvement for observing a assortment of radiation types every bit good as feeling assorted physical parametric quantities such as temperature and force per unit area. For illustration, diamond thermal resistors have been proposed for temperature measuring in hostile environments such as chemical processing, gearbox oil, and cryogenies. The piezoresistive consequence of diamond has been used to feel force per unit area, and p-type CVD polycrystalline diamond is reported to hold a big piezoresistive gage factor [ 12 ] . Diamond is highly radiation hard, with a 55-eV supplanting energy for a C atom in the diamond lattice. It besides acts as an ionizing radiation sensor and is hence of involvement for radiation measurings where exposure to big doses is required. The big set spread of diamond make it of involvement as a UV sensor, based on photoconduction, which is blind to seeable visible radiation. ( Reinhard )